The
priorities were to bring about a broad ceasefire, stop so-called Islamic State
(IS) and increase aid, he said.
Mr de Mistura's announcement came as 23 people were
reportedly
killed in an attack on a rebel checkpoint in Aleppo.
A suicide bomber driving a fuel lorry targeted a checkpoint run
by the Islamist rebel group Ahrar al-Sham, the Syrian Observatory for Human Rights
said.
Four of the group's commanders and four civilians were believed
to be among the dead, according to the UK-based monitoring group.
It is not known who carried out the attack, in which dozens of
people were also wounded.
More than
250,000 people have died in Syria in the almost five years of fighting since
opposition protests against the rule of President Bashar al-Assad began.
Staffan de Mistura
Mr de Mistura said the "proximity talks" would be
indirect to start with, with negotiators ferrying messages between
representatives of the warring parties.
The talks
had been delayed by disputes over who should attend, he said, but he added that
he expected invitations to be sent out on Tuesday.
Participation
by IS and the al-Qaeda's affiliate in Syria, al-Nusra Front, had been ruled
out, he said, but discussions about other rebel groups were continuing.
Turkey has warned that participation by Syrian Kurdish forces,
which it considers to be "terrorists", could cause the talks to fail.
Mr de Mistura said the first phase of negotiations would last
between two and three weeks.
He warned the talks would be stormy, with "a lot of
posturing, a lot of walk-outs and walk-ins".
Issues of governance, a constitutional review and future
elections would also be on the agenda, he added.


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